805314-84-5

Basic information

• Product Name: Acetic acid, (4-methoxyphenoxy)-, 3-(1,1-dimethylethyl)-5-formyl-4-hydroxyphenyl ester
• CAS NO: 805314-84-5
• Molecular Formula: C20H22O6
• Molecular Weight: 358.391
• Mol File: 805314-84-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid, (4-methoxyphenoxy)-, 3-(1,1-dimethylethyl)-5-formyl-4-hydroxyphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, (4-methoxyphenoxy)-, 3-(1,1-dimethylethyl)-5-formyl-4-hydroxyphenyl ester(805314-84-5)
• EPA Substance Registry System: Acetic acid, (4-methoxyphenoxy)-, 3-(1,1-dimethylethyl)-5-formyl-4-hydroxyphenyl ester(805314-84-5)

Safety Data

• Hazardous Substances Data: 805314-84-5(Hazardous Substances Data)

Upstream product

• 192803-36-4 5-benzyloxy-3-tert-butyl-2-hydroxy-benzaldehyde 
• 1948-33-0 tert-butylhydroquinone 
• 150-76-5 4-methoxy-phenol 
• 3421-95-2 4-(benzyloxy)-2-(tert-butyl)phenol 
• 1877-75-4 2-(4-methoxyphenoxy)acetic acid 
• 192803-37-5 3-tert-butyl-2,5-dihydroxybenzaldehyde 

Relevant articles and documents

Polymeric salen-Ti(IV) or V(V) complex catalyzed asymmetric synthesis of O-acetylcyanohydrins from KCN, Ac2O and aldehydes

Polymeric salen-Ti(IV) and V(V) complexes were employed in the enantioselective O-acetyl cyanation of aldehydes with potassium cyanide and acetic anhydride. The crosslinked polymeric salen-Ti(IV) catalyst exhibited good activities and enantioselectivities, up to 91% ee with 99% conversion was obtained at -20°C with 1 mol% of catalyst (based on bimetallic catalytic unit). Moreover, six consecutive recyclings with the easily recovered crosslinked polymeric catalyst showed no obvious decrease in either activity or enantioselectivity. Linear polymeric salen-V(V) catalyst showed good catalytic efficiency too, up to 94% ee with 99% conversion was obtained at -42°C with 5 mol% of catalyst. Graphical Abstract.