80641-31-2

Upstream product

• 80641-24-3 Methyl β-Hydroxy-α-cyano-p-nitrocinnamate 
• 122-04-3 4-nitro-benzoyl chloride 
• 1121-70-6 sodium 4-methylphenoxide 
• 106-44-5 p-cresol 
• 80641-22-1 methyl (E)-β-chloro-α-cyano-p-nitrocinnamate 

Relevant academic research and scientific papers

Stereochemistry of Substitution of Good Nucleofuges at the Stereoconvergence Region as a Tool for Investigating the Rapid Step of Nucleophilic Vinylic Substitution

Methyl-α-cyano-β-X-p-nitrocinnamates (5; X=Cl, Br, OTs, OTf) were prepared.The five (E) isomers and the (Z) isomers (X=Cl, Br, OMs) were separated and their structures assigned.Substitution of the eight substrates by p-MeC6H4S-M+ and

Nucleophilic Attacks on Carbon-Carbon Double Bonds. 28.1,2 Complete and Partial Stereoconversion in the Substitution of Methyl (E)- and (Z)-β-Chloro-α-cyano-p-nitrocinnamates by Nucleophiles

Methyl (E)- and (Z)-β-chloro-α-cyano-p-nitrocinnamates 5-E and 5-Z were prepared and separated.The stereochemistry of the substitution of the chlorine by nucleophiles was invastigated in MeCN, MeOH, or their mixtures.Reaction with p-toluenethiolate ion ga