80641-24-3

Upstream product

• 122-04-3 4-nitro-benzoyl chloride 
• 105-34-0 methyl 2-cyanoacetate 

Downstream Products

• 80641-22-1 methyl (E)-β-chloro-α-cyano-p-nitrocinnamate 
• 80641-23-2 methyl (Z)-β-chloro-α-cyano-p-nitrocinnamate 
• 112220-57-2 Sodium; (Z)-2-cyano-2-methoxycarbonyl-1-(4-nitro-phenyl)-ethenolate 
• 80641-27-6 Methyl (E)-α-Cyano-β-methoxy-p-nitrocinnamate 
• 80641-30-1 Methyl (E)-α-Cyano-β-(p-methylphenoxy)-p-nitrocinnamate 
• 80641-31-2 Methyl (Z)-α-Cyano-β-(p-methylphenoxy)-p-nitrocinnamate 
• 80641-26-5 Methyl (Z)-α-Cyano-p-nitro-β-(p-tolylthio)cinnamate 

Relevant academic research and scientific papers

Nucleophilic Attacks on Carbon-Carbon Double Bonds. 28.1,2 Complete and Partial Stereoconversion in the Substitution of Methyl (E)- and (Z)-β-Chloro-α-cyano-p-nitrocinnamates by Nucleophiles

Methyl (E)- and (Z)-β-chloro-α-cyano-p-nitrocinnamates 5-E and 5-Z were prepared and separated.The stereochemistry of the substitution of the chlorine by nucleophiles was invastigated in MeCN, MeOH, or their mixtures.Reaction with p-toluenethiolate ion ga