80705-17-5Relevant academic research and scientific papers
Reaction de RFI (RF=CnF2n+1, n=4,6,8) en presence de zinc avec les acetates de vinyle et d'allyle: application a la synthese de diols a chaines fluorees
Laurent, Ph.,Blancou, H.,Commeyras, A.
, p. 161 - 171 (2007/10/02)
The effect of various solvents on the addition of RFI to vinyl and allyl acetates in the presence of zinc has been studied.The orientation of the reaction towards a dimerisation process has allowed the synthesis of the 1,4-bis(perfluoroalkyl)butane-2,3-diols and 2,3-bis(perfluoroalkyl methyl)butane-1,4-diols in quite good yield.
Synthesis of fluoroalkyl ethanal: R(F)CH2CHO
Laurent,Blancou,Commeyras
, p. 2489 - 2492 (2007/10/02)
Aldehydes R(F)CH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. R(F)CH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, R(F)CH2CHO and its acylal or acetal derivatives are obtained in good yields.
