80705-86-8Relevant academic research and scientific papers
REACTION OF PROPOSED PHOSPHOROTHIOLATE S-OXIDE INTERMEDIATES WITH ALCOHOLS
Segall, Yoffi,Casida, John E.
, p. 209 - 212 (2007/10/02)
S-Oxide 2 is an extremely reactive intermediate.Its phosphorylation vs rearrangement rates, strongly depend upon the nature of the nucleophile.
OXIDATIVE CONVERSION OF PHOSPHOROTHIOLATES TO PHOSPHINYLOXYSULFONATES PROBABLY VIA PHOSPHOROTHIOLATE S-OXIDES
Segall, Yoffi,Casida, John E.
, p. 139 - 142 (2007/10/02)
Phosphorothiolate S-oxides and their phosphinyloxysulfenate rearrangement products are probable intermediates in the facile conversion of phosphorothiolates to phosphinyloxysulfonates on peracid oxidation.They may also be intermediates in the biological oxidation of phosphorothiolates.
