80804-82-6Relevant academic research and scientific papers
Grubbs-Hoveyda Second-Generation Catalysts Activated by the Introduction of a Light Fluorous Tag onto the Bidentate Ligands
Kobayashi, Yuki,Suzumura, Naoki,Tsuchiya, Yuki,Goto, Machiko,Sugiyama, Yuya,Shioiri, Takayuki,Matsugi, Masato
supporting information, p. 1796 - 1807 (2017/04/06)
Various novel Grubbs-Hoveyda second-generation catalysts activated by a fluorous tag on the ligands were prepared. The catalyst bearing the 1-naphthyl group on the bidentate ligand exhibited the highest catalytic activity among the studied catalysts for the ring-closing-metathesis reaction of diethyl 2-allyl-2-(2-methylallyl)malonate.
Easy two-step synthesis of new tris(perfluoroalkylphenyl)phosphites
Mathivet, Thomas,Monflier, Eric,Castanet, Yves,Mortreux, Andre,Couturier, Jean-Luc
, p. 9411 - 9414 (2007/10/03)
A general route for the synthesis of tris(perfluoroalkylphenyl)phosphites from halophenol derivatives and 1- iodoperfluorooctane is described. The stability arid the solubility of these new compounds are reported.
Perfluoroalkyl- and perfluoroalkylether-substituted aromatic phosphates and phosphonates
Paciorek,Lin,Masuda
, p. 55 - 61 (2007/10/03)
A series of phosphates and phosphonates, (p-RfC6H4O)3 xP(O) (OC6H5)x and (p-RfC6H4O)3 xP(O) (C6H
DIRECT PERFLUOROALKYLATION OF FUNCTIONALIZED BENZENES WITH PERFLUOROALKYL HALIDES AND COPPER BRONZE
Fuchikami, Takamasa,Ojima, Iwao
, p. 541 - 556 (2007/10/02)
Perfluoroalkyl halides were found to react with functionalized benzenes in the presence of copper bronze to give the corresponding perfluoroalkylated products directly in moderate to good yields.The reaction may involve' active species' other than perfluoroalkylcopper species.Synthetic utility and possible mechanisms of the present one-step reaction are discussed.
PERFLUOROALKYLATION OF AROMATIC COMPOUNDS WITH RfI(Ph)OSO2CF3
Umemoto, Teruo,Kuriu, Yuriko,Shuyama, Hideo
, p. 1663 - 1666 (2007/10/02)
Perfluoroalkylation of various aromatic compounds with perfluoroalkylphenyliodonium trifluoromethanesulfonate (FITS) under mild conditions was described.The reactivity of other perfluoroalkyliodonium salts was also examined.
