80806-68-4

Basic information

• Product Name: 3-(PERFLUOROHEXYL)PROPANOL
• Synonyms: 3-(PERFLUOROHEXYL)PROPANOL;3-(PERFLUOROHEXYL)PROPANOL-1;4,4,5,5,6,6,7,7,8,8,9,9,9-TRIDECAFLUORO-1-NONANOL;1H,1H,2H,2H,3H,3H-PERFLUORONONAN-1-OL;DAIKIN A-1630;3-(Perfluoro-n-hexyl)propanol;3-(Perfluorohexyl) Propyl Alcohol;3-(perfluorohexyl)propanol,4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononan-1-ol
• CAS NO: 80806-68-4
• Molecular Formula: C₉H₇F₁₃O
• Molecular Weight: 378.13
• Mol File: 80806-68-4.mol
• Article Data: 16

Chemical Properties

• Melting Point: -3°C(lit.)
• Boiling Point: 80 °C
• Flash Point: 50℃
• Appearance: /
• Density: 1.629
• Vapor Pressure: 0.857mmHg at 25°C
• Refractive Index: 1.329
• Storage Temp.: Refrigerator
• Solubility: Benzene (Sparingly), Chloroform (Sparingly), DMSO (Slightly), Ethyl Acetate (Sli
• PKA: 14.83±0.10(Predicted)
• CAS DataBase Reference: 3-(PERFLUOROHEXYL)PROPANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(PERFLUOROHEXYL)PROPANOL(80806-68-4)
• EPA Substance Registry System: 3-(PERFLUOROHEXYL)PROPANOL(80806-68-4)

Safety Data

• Hazard Codes: Xi
• RIDADR: UN 1987 3/PG III
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 80806-68-4(Hazardous Substances Data)

Usage

Uses

1H,1H,2H,2H,3H,3H-Tridecafluoro-1-nonanol is used in preparation of fluoroalkyl vinyl ether by reaction of fluorinated alcohol with divinyl ether and/or trivinyl ether.

InChI:InChI=1/C9H7F13O/c10-4(11,2-1-3-23)5(12,13)6(14,15)7(16,17)8(18,19)9(20,21)22/h23H,1-3H2

Upstream product

• 67-56-1 methanol 
• 25291-17-2 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene 
• 355-43-1 n-perfluorohexyl iodide 
• 165281-74-3 Ethyl 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodononanoate 
• 60023-26-9 Ethyl 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononanoate 
• 80793-18-6 3-(perfluorohexyl)prop-1-ene 
• 38550-44-6 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-1-iodononan-1-ol 
• 107-18-6 allyl alcohol 
• 83310-90-1 2-Iodo-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl acetate 
• 89889-20-3 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-9-iodononane 
• 83311-03-9 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl acetate 

Downstream Products

• 881543-65-3 4,4,5,5,6,6,7,7,8,8,9,9,9tridecafluorononyl-oxybenzene 
• 110980-12-6 Methyl 3-perfluorohexyl-propyl (-)-1,4-dihydro-2,6-dimethyl-4-(3-nitrophenyl)-pyridine-3,5-dicarboxylate 
• 34451-26-8 2-perfluorohexylethanethiol 
• 462996-01-6 bis(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl) diazodicarboxylate 
• 910660-96-7 Bis-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl)-thiocarbamic acid O-((2R,4aR,6S,7R,8S,8aR)-7-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl) ester 
• 910660-90-1 bis-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl)-thiocarbamic acid O-(1-methyl-2-phenyl-ethyl) ester 
• 910660-79-6 benzyl-bis-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl)-amine 
• 89889-20-3 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-9-iodononane 
• 228570-06-7 toluene-4-sulfonic acid 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl ester 
• 27854-30-4 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononanoic acid 
• 83311-03-9 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl acetate 
• 1245062-18-3 3-(perfluorohexyl)propyl 4-(3-hydroxypropyloxy)benzoate 
• 1331781-75-9 3-(perfluorohexyl)propyl 4-(3-acryloyloxypropyloxy)benzoate 
• 1245062-17-2 3-(perfluorohexyl)propyl 4-(2-propenyloxy)benzoate 

Relevant articles and documents

Hydroperfluoroalkylation of alkenes using R(f)I/YbCl3(cat.)/Zn system

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A fluorous ethylenediamine promoted direct C-H arylation of unactivated arenes with aryl halides

A novel and recyclable fluorous ethylenediamine was prepared. Together with potassium tert-butoxide, the fluorous ethylenediamine showed a good activity in promoting the coupling of aryl halides with benzene derivatives without the aid of transition-metal catalysts. Furthermore, a chain homolytic aromatic substitution mechanism was proposed in this paper.

Mesophase structure of low-wetting liquid crystalline polyacrylates with new perfluoroalkyl benzoate side groups

The synthesis, thermal behavior, bulk microstructure, and wettability of new polyacrylates carrying spaced 4-perfluorohexylpropyl benzoate and 4-perfluorooctylpropyl benzoate units in the side groups were Investigated. X-ray diffraction analysis proved the formation of different smectic mesophases (SmI2, SmF2, and SmC2) and the evolution of their structures and lattice parameters with temperature. The mesophase polymorphic behavior depended on the length of the perfluorinated chain segment in the repeat unit. The electron density profiles along the smectic layer normal were drawn and provided a deeper insight into the packing of the side chains in a tilted, double layer structure. Thin polymer films were cast from solution, and their low wettability was established by measurements of contact angles with different probing liquids. We suggest that the hydrophobicity and lipophobicity of the films are enhanced by the mesophase surface structure which is mediated by the high-order, mesophase bulk structure.

3-(Perfluoroalkyl)propanols: Valuable building blocks for fluorous chemistry

2-Iodo-3-(perfluoroalkyl)propanols are obtained in excellent yields and several-hundred-gram quantities by the controlled radical addition of commercially available n-perfluoroalkyl and perfluoroisoalkyl iodides to allyl alcohol. Their consecutive reduction with hydrazine hydrate and Raney nickel catalyst in methanol afforded the corresponding 3-(perfluoroalkyl)propanols in high yields and purity. Georg Thieme Verlag Stuttgart.