80816-25-7

Upstream product

• 57433-61-1 2-bromocyclohexyl 2-bromoethyl ether 
• 930-68-7 cyclohexenone 
• 109-92-2 ethyl vinyl ether 
• 111-34-2 -butyl vinyl ether 
• 822-67-3 Cyclohex-2-enol 
• 765-12-8 Triethylene glycol divinyl ether 
• 110-83-8 cyclohexene 
• 7012-38-6 2-chlorocyclohexyl 2-chloroethyl ether 

Downstream Products

• 80816-26-8 1-(2-cyclohexenyl)-4-phenyl-3-butyn-2-ol 
• 123729-77-1 (E)-3-(3-nitroallyl)cyclohexene 
• 3675-31-8 2-(cyclohex-2-enyl)acetic acid 
• 16452-34-9 2-(cyclohex-2-enyl)ethanol 
• 96333-87-8 1-(2-cyclohexenyl)-2-propanol 
• 19656-95-2 2-cyclohexenylacetaldehyde 

Relevant academic research and scientific papers

Tandem Pd(II)-catalyzed vinyl ether exchange-claisen rearrangement as a facile approach to γ,δ-unsaturated aldehydes

(Chemical Equation Presented) A sequential allyl vinyl ether formation-Claisen rearrangement process catalyzed by a palladium(II)- phenanthroline complex is reported. The effects of allylic alcohol structure, type of vinylating agent, and palladium catalysts are discussed. This method provides a convenient approach to γ,δ unsaturated aldehydes under mild conditions that avoid the use of toxic Hg(II) catalysts. The new methodology has been successfully demonstrated on the kilogram scale.

Synthesis of allyl and alkyl vinyl ethers using an in situ prepared air-stable palladium catalyst. Efficient transfer vinylation of primary, secondary, and tertiary alcohols

An air-stable palladium catalyst formed in situ from commercially available components efficiently catalyzed the transfer vinylation between butyl vinyl ether and various allyl and alkyl alcohols to give the corresponding allyl and alkyl vinyl ethers in 61-98% yield in a single step.

Mechanism of chorismate mutase: Contribution of conformational restriction to catalysis in the Claisen rearrangement

The mechanism of the enzyme- and antibody-catalyzed Claisen rearrangement of chorismate to prephenate was investigated experimentally on model compounds and by using quantum chemistry calculations at the Becke3LYP/6-31G* level of theory. Conformational re

Cohalogenation of alkenes in ethylene oxide: Efficient methodology for the preparation of allyl vinyl ether precursors of γ,δ-unsaturated aldehydes

An investigation of the cohalogenation-dehydrohalogenation sequence as a method for the preparation of allyl vinyl ethers from simple olefins has been performed. Alkenes 1a-k react with bromide or chloride in the presence of ethylene oxide at -80°C to for

A New Acylative Cycloaddition Reaction

A new procedures for the intramolecular nitrile oxide cycloaddition is described; the procedure involves the generation of a nitrile oxide resulting from the conjugate addition of an isocyanide to a nitroalkene, and subsequent trapping with an alkene.