808168-82-3Relevant academic research and scientific papers
Ruthenium arene derivatives with PN hemilabile ligands. P-C cleavage and phosphine to phosphinite transformation
Caballero, Agustin,Jalon, Felix A.,Manzano, Blanca R.,Espino, Gustavo,Perez-Manrique, Mercedes,Mucientes, Antonio,Poblete, Francisco J.,Maestro, Miguel
, p. 5694 - 5706 (2004)
The synthesis of ruthenium arene derivatives with hemilabile ligands was investigated. An unexpected reactivity of the ligand was observed during the course of the synthesis which was transformed by the reaction with methanol into diarylphosphinite. The transformation of [RuCl2(arene)(κ] 1-PN)] type neutral derivatives in to the cationic species [RuCl(arene)κ2-PN)]X was achieved. The protonation of the neutral derivatives with HBF4 resulted in the formation of [RuCl 2(arene)(κ1-PNH)]BF4 which exhibited a hydrogen bond.
