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80822-10-2

[ruthenium(II)Cl(η5-C5H5)(PH(C6H5)2)(P(C6H5)3)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 80822-10-2 Structure

  • Basic information

    1. Product Name: [ruthenium(II)Cl(η5-C5H5)(PH(C6H5)2)(P(C6H5)3)]
    2. Synonyms:
    3. CAS NO:80822-10-2
    4. Molecular Formula:
    5. Molecular Weight: 650.102
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 80822-10-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [ruthenium(II)Cl(η5-C5H5)(PH(C6H5)2)(P(C6H5)3)](CAS DataBase Reference)
    10. NIST Chemistry Reference: [ruthenium(II)Cl(η5-C5H5)(PH(C6H5)2)(P(C6H5)3)](80822-10-2)
    11. EPA Substance Registry System: [ruthenium(II)Cl(η5-C5H5)(PH(C6H5)2)(P(C6H5)3)](80822-10-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 80822-10-2(Hazardous Substances Data)

80822-10-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 80822-10-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,0,8,2 and 2 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 80822-10:
(7*8)+(6*0)+(5*8)+(4*2)+(3*2)+(2*1)+(1*0)=112
112 % 10 = 2
So 80822-10-2 is a valid CAS Registry Number.

80822-10-2Downstream Products

80822-10-2Relevant articles and documents

Substitution reactions of CpRu (PPh3)2Cl with PPh2H and dppa

Geicke,Lorenz,Engel,Polborn

, p. 157 - 161 (1998)

One PPh3 group of CpRu(PPh3)2Cl is easily substituted by PPh2H to give the asymmetrical complex CpRu(PPh3)(PPh2H)Cl (1) in a very good yield. Attempts to form the λ4-phosphanediyl complex CpRu (PPh3)=PPh2 (1′) by selective dehydrohalogenation of 1 failed. However, by using one equivalent of the chelating diphosphine dppa two PPh3 ligands are substituted to yield CpRu(dppa)Cl (2). With an excess of dppa the reaction yielded the N-iminophosphoranyl-substituted dppa complex CpRu{(PPh2)2NPPh2=NH}Cl (3) and PPh2H. 1H, 13C{1H} and 31P{1H} NMR, IR and mass spectra of 1-3 are given. Crystals of 1 are monoclinic, space group P21/c with a=11.8446(12), b= 14.502(3), c= 17.504(2) A and β=95.55(9)°, Z=4 and R=0.0270 for 4299 observed reflections. Crystals of 2 are monoclinic, space group P21/c with a=10.7616(14), b=18.263(4), c= 13.859(2) A and β=110.41(1)°, Z=4 and R=0.0327 for 4227 observed reflections.

Synthesis, properties and crystal structures of pentamethylcyclopentadienyl- and cyclopentadienyl-ruthenium(II) diphenylphosphine complexes

Lubian, Roman Torres,Paz-Sandoval, M. Angeles

, p. 17 - 29 (2007/10/03)

The synthesis, characterization and single-crystal structure determination of chiral compounds (η5-C5R5)Ru(PHPh2)(PPh3)Cl (R=H 3, R=Me 4) and prochiral Cp * Ru(PHPh2)2Cl (6) are described. Compound 6 has been available from reaction of PHPh2 and several starting materials. The X-ray structure comparison between 3, 4 and 6 allowed us to compare the influence of the phosphine, Cp and Cp * ligands in these half-sandwich compounds. In addition, a structural investigation was carried out on Cp * Ru(NBD)Cl (7).

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