808739-72-2Relevant articles and documents
First total synthesis of (±)-prelunularin
Comas, Horacio,Pandolfi, Enrique
, p. 2493 - 2498 (2007/10/03)
The first total synthesis of (±)-prelunularin is described employing an intramolecular aldol addition/sulfinate elimination tandem reaction. Investigations on the mechanism of the one-pot cyclization reaction using time-dependent NMR spectroscopy suggested that the sulfinate elimination took place before the intramolecular ring-closing aldol addition.