80884-12-4Relevant academic research and scientific papers
Regioselective synthesis of multisubstituted pyrazoles via cyclocondensation of β-thioalkyl-α,β-unsaturated ketones with hydrazines
Jin, Weiwei,Yu, Haifeng,Yu, Zhengkun
experimental part, p. 5884 - 5887 (2011/12/02)
Multisubstituted pyrazoles were efficiently synthesized by cyclocondensation of β-thioalkyl-α,β-unsaturated ketones with hydrazines under relatively mild conditions. A one-pot synthetic protocol through tandem Liebeskind-Srogl cross-coupling/cyclocondensation using a-oxo ketene dithioacetals as the starting materials was also realized for the same purpose.
Layered zirconium sulfophenyl phosphonate as heterogeneous catalyst in the synthesis of pyrazoles and 4,5,6,7-tetrahydro-1(2)H-indazoles
Curini, Massimo,Rosati, Ornelio,Campagna, Valerio,Montanari, Francesca,Cravotto, Giancarlo,Boccalini, Mauro
, p. 2927 - 2930 (2007/10/03)
Pyrazoles and tetrahydroindazoles may be prepared by condensation of 1,3-diones and hydrazines under layered zirconium sulfophenyl phosphonate catalysis, in solvent-free conditions. Georg Thieme Verlag Stuttgart.
