80956-52-1Relevant academic research and scientific papers
Cobaltocene-Catalyzed Reaction of Carbon Dioxide with Propargyl Alcohols
Inoue, Yoshio,Ishikawa, Jiro,Taniguchi, Masaaki,Hashimoto, Harukichi
, p. 1204 - 1206 (1987)
The reaction of carbon dioxide with α-ethynyl tertiary alcohols has been catalyzed by cobaltocene to give α-methylene cyclic carbonates in good yields. α-Ethynyl primary or secondary alcohols give noncyclic alkyl carbonates in fair yields.
Effective guanidine-catalyzed synthesis of carbonate and carbamate derivatives from propargyl alcohols in supercritical carbon dioxide
Ca', Nicola Della,Gabriele, Bartolo,Ruffolo, Giuseppe,Veltri, Lucia,Zanetta, Tito,Costa, Mirco
supporting information; experimental part, p. 133 - 146 (2011/04/18)
The reactions of propargyl alcohols with carbon dioxide in supercritical carbon dioxide or in acetonitrile with gaseous carbon dioxide in the presence of organic bases as catalysts have been examined. Bicyclic guanidines are effective catalysts for the formation of α-methylene cyclic carbonates under mild reaction conditions. Oxoalkyl carbonates, oxoalkyl carbamates or α-methyleneoxazolidinones are obtained in high yields and good selectivities in one-step starting from propargyl alcohols and an external nucleophile (alcohols or amines) using bicyclic guanidines as catalysts in supercritical carbon dioxide. Propargylic diols under the same reaction conditions underwent a rearrangement process instead of carbon dioxide insertion whereas in the presence of an external nucleophile the formation of oxocarbonates, oxocarbamates or cyclic carbamates was achieved in satisfactory yields.
