
Bulletin of the Chemical Society of Japan p. 1204 - 1206 (1987)
Update date:2022-08-03
Topics:
Inoue, Yoshio
Ishikawa, Jiro
Taniguchi, Masaaki
Hashimoto, Harukichi
The reaction of carbon dioxide with α-ethynyl tertiary alcohols has been catalyzed by cobaltocene to give α-methylene cyclic carbonates in good yields. α-Ethynyl primary or secondary alcohols give noncyclic alkyl carbonates in fair yields.
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