80991-15-7Relevant academic research and scientific papers
NEW APPROACH TO ASPIDOSPERMINE TOTAL SYNTHESIS USING ORGANOIRON COMPLEXES
Pearson, Anthony J.
, p. 4033 - 4036 (1981)
The conversion of p-ethylanisole, via the tricarbonyl(diene)-iron complex (3), to the bicyclic amino ketone (2), which is a known precursor for aspidospermine total synthesis, is described.The synthetic route demonstrates the stability of the diene-Fe(CO)3 unit to a number of useful synthetic transformations.
Total Synthesis of (+/-)-Limaspermine and Formal Synthesis of (+/-)-Aspidospermine using Organoiron Complexes
Pearson, Anthony J.,Rees, David C.
, p. 2467 - 2476 (2007/10/02)
The total synthesis of the C-18 oxygenated aspidosperma alkaloid (+/-)-limaspermine (3) is described using tricarbonyliron (15) as a readily available ring C precursor.A formal synthesis
