Tetrahedron Letters p. 4033 - 4036 (1981)
Update date:2022-09-26
Topics:
Pearson, Anthony J.
The conversion of p-ethylanisole, via the tricarbonyl(diene)-iron complex (3), to the bicyclic amino ketone (2), which is a known precursor for aspidospermine total synthesis, is described.The synthetic route demonstrates the stability of the diene-Fe(CO)3 unit to a number of useful synthetic transformations.
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