81028-04-8

Upstream product

• 78513-07-2 ((2R,3S)-3-((benzyloxy)methyl)oxiran-2-yl)methanol 
• 108-98-5 thiophenol 
• 81028-03-7 (Z)-4-benzyloxy-but-2-en-1-ol 

Downstream Products

• 146862-78-4 (E)-methyl cis-4,5-(isopropylidenedioxy)-6-(benzyloxy)-2-hexenoate 
• 146862-77-3 (Z)-methyl cis-4,5-(isopropylidenedioxy)-6-(benzyloxy)-2-hexenoate 
• 81028-15-1 (1S,2S)-1-((4S,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propane-1,2,3-triol 
• 81028-15-1 (1R,2S)-1-((4S,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propane-1,2,3-triol 
• 81028-15-1 (1R,2R)-1-((4S,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propane-1,2,3-triol 
• 81028-13-9 (E)-3-((4S,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol 
• 81028-13-9 (Z)-3-((4S,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol 
• 81028-14-0 [(2R,3S)-3-((4R,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranyl]-methanol 
• 81028-14-0 [(2R,3R)-3-((4R,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranyl]-methanol 
• 81028-14-0 [(2S,3R)-3-((4R,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranyl]-methanol 
• 81801-08-3 4-O-benzyl-2,3-O-isopropylidene-aldehydo-D-erythrose 
• 81028-07-1 (2S,3S)-1-(benzyloxy)butane-2,3,4-triol 
• 502481-96-1 (2S,3R)-4-benzyloxy-2,3-(propane-2,2-dioxy)-1-butanol 
• 81028-05-9 Acetic acid ((4R,5R)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-phenylsulfanyl-methyl ester 

Relevant academic research and scientific papers

Trapping of Payne rearrangement intermediates with arylselenide anions

The intermediate epoxy alcohols prepared via a Payne rearrangement can be trapped with arylselenide anions, giving mixtures of ring-opened products. The 1-arylseleno-2,3-diols are generally favored over the 3-arylseleno-1,2-diols in this process although

Synthesis of Saccharides and Related Polyhydroxylated Natural Products. 1. Simple Alditols

A new approach to sugar synthesis is demonstrated through syntheses of tetritols, pentitols, and hexitols; titanium-catalyzed asymmetric epoxidation and a new selective opening reaction of 2,3-epoxy alcohols play essential roles.