81033-21-8Relevant academic research and scientific papers
Reactions of Carbonyl Sulphide with Hydrated Ruthenium Trichloride and Its Complexes in Presence and Absence of Triphenylphosphine, Triphenylarsine and Triphenylstibine
Datta, S.,Shukla, S. K.,Agarwala, U. C.
, p. 985 - 989 (2007/10/02)
The reactions of COS with some ruthenium(II) and ruthenium(III) complexes, and with RuCl3*xH2O in the presence and absence of excess of PPh3, AsPh3 and SbPh3 have been investigated.The products have been characterized by elemental analyses, infrared spectra, conductivity measurements, magnetic moments and molecular weight measurements (wherever possible).In most of the cases COS acts as a carbonylating agent but in some it forms S=PPh3 or S=AsPh3 complexes.Some thiocarbonyl and molecular COS complexes are also reported.
