81034-12-0Relevant academic research and scientific papers
FORMATION OF 1,1-DITHIODICARBOXYLIC ACID ESTERS FROM CYCLIC KETONES, CARBON DISULFIDE, AND LITHIUM METHOXIDE
Fujinami, Tatsuo,Wakuda, Kazuo,Takahashi, Noriyuki,Sakai, Shizuyoshi
, p. 123 - 126 (2007/10/02)
Methyl esters of 1,1-dithiodicarboxylic acids were formed by the reaction of cyclic ketones with lithium methoxide and carbon disulfide in tetrahydrofuran followed by the treatment with methyl iodide.The reaction proceeds via dithiocarboxylation and carbonyl carbon-carbon bond cleavage through an inverse Dieckmann-type reaction.
