81066-95-7Relevant academic research and scientific papers
PREPARATION OF SUBSTITUTED 5-PYRIMIDINECARBONITRILES AND 1,3,5-TRIAZINES FROM ALKYL N-CYANOIMIDATES
Perez, Miguel A.,Soto, Jose L
, p. 463 - 468 (2007/10/02)
Sodium methoxide induced the cyclization of alkyl N-cyanoimidates 1 with propanedinitrile affording the 5-pyrimidinecarbonitriles 2.The reaction of 1 with methyl cyanoaetate led to the methyl 3-propenoates 7 and the 2,4-dioxo-5-pyrimidinecarbonitrile 8.An analogous cyclization of 1 with cyanamide yielded the 1,3,5-triazines 10.
