81095-47-8Relevant academic research and scientific papers
Silanes in organic synthesis. 15. Silicon-directed hydride abstraction from ( 2-(trimethylsilyl )-1,3-cyclohexadiene )iron tricarbonyl complexes and nucleophilic addition to the derived cations
Paquette, Leo A.,Daniels, Rhys G.
, p. 757 - 760 (1982)
Several (2-(trimethylsilyl)-1,3-cyclohexadiene)iron tricarbonyl complexes were prepared and treated with triphenylcarbenium cation. In all cases, hydride abstraction proved to be completely regiospecific to deliver only silyl-symmetric η5 catio
Synthesis, reactivity, and electronic structure of (2-(Trimethylsilyl)-1,3-cyclohexadiene)iron tricarbonyl complexes
Paquette, Leo A.,Daniels, Rhys G.,Gleiter, Rolf
, p. 560 - 567 (2008/10/08)
Reaction of several 2-(trimethylsilyl)-1,3-cyclohexadiene derivatives with excess iron pentacarbonyl in refluxing di-n-butyl ether produced the unrearranged Fe(CO)3 complexes. Hydride abstraction from these organometallics with triphenylcarbeni
