Silanes in organic synthesis. 15. Silicon-directed hydride abstraction from ( 2-(trimethylsilyl )-1,3-cyclohexadiene )iron tricarbonyl complexes and nucleophilic addition to the derived cations

DOI: 10.1021/om00065a018

Source and publish data:

Organometallics p. 757 - 760 (1982)

Update date:2022-08-02

Topics:

Authors:

Paquette, Leo A.

Daniels, Rhys G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00065a018

Several (2-(trimethylsilyl)-1,3-cyclohexadiene)iron tricarbonyl complexes were prepared and treated with triphenylcarbenium cation. In all cases, hydride abstraction proved to be completely regiospecific to deliver only silyl-symmetric η⁵ catio

Full text of DOI:10.1021/om00065a018

Products guided by the article

Product name:(C₆H₄(CH₃)2(CH(CO₂CH₂CH₃)SO₂C₆H₅)Si(CH₃)3)Fe(CO)3

Cas No:81095-47-8

R&D Labs maybe for 81095-47-8

SICHUAN TONGSHENG AMINOACID CO.LTD

website:http://www.aminoacid.cc

Contact:86-838-2274206/2850606

Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China
Wuxi Morality Chemical Co., Ltd(expird)

Contact:

Address:B/7F, 321th WuYun Rd, Wanda Plaza, Wuxi City, 214174, China
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
Hangzhou Maytime Bio-Tech Co.,Ltd.

website:http://www.maytime.com.cn

Contact:+86-571-88925295 88920965

Address:NO.2-1701 Ganghui Central Ningwei Street, Xiaoshan Hangzhou Zhejiang China
GLD peptide scientific lnc.

Contact:21-7631221 15884421033

Address:326 Science and technology,Shanghai,China

Relevant to this article

Doi:10.1021/ja01235a033
(1944)
REGIOSELECTIVE TRANSFORMATION OF INTERNAL ALKYNES TO UNSYMMETRICAL KETONES. NOVEL ROUTES TO KEY INTERMEDIATES FOR THE SYNTHESIS OF CARBAPENEM AND CARBACEPHEM SKELETONS

Doi:10.1016/S0040-4039(01)92353-6
(1981)
Diastereoselective addition of organocerium(III) reagents derived from 3-substituted propargyl bromides to aldehydes

Doi:10.1055/s-2006-947349
(2006)
Synthesis of methyl 2-isocyano-3-[3(1H)-indolyl]acrylate and related compounds from 3-(aminomethylene)-3H-indoles

Doi:10.1248/cpb.30.158
(1982)
Novel 1,3,4-oxadiazole compounds inhibit the tyrosinase and melanin level: Synthesis, in-vitro, and in-silico studies

Doi:10.1016/j.bmc.2021.116222
(2021)
Mechanism of elimination rections. 40. Attempted study of stereochemistry of elimination from 2-(p-nitrophenyl)ethyltrimmethylammonium ion. Base-promoted cis-trans isomerization of p-nitrostyrene-β-d¹

Doi:10.1139/v86-172
(1986)

Article Doi