Silanes in organic synthesis. 15. Silicon-directed hydride abstraction from ( 2-(trimethylsilyl )-1,3-cyclohexadiene )iron tricarbonyl complexes and nucleophilic addition to the derived cations

DOI: 10.1021/om00065a018

Source and publish data:

Organometallics p. 757 - 760 (1982)

Update date:2022-08-02

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Authors:

Paquette, Leo A.

Daniels, Rhys G.

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Article abstract of DOI:10.1021/om00065a018

Several (2-(trimethylsilyl)-1,3-cyclohexadiene)iron tricarbonyl complexes were prepared and treated with triphenylcarbenium cation. In all cases, hydride abstraction proved to be completely regiospecific to deliver only silyl-symmetric η⁵ catio

Full text of DOI:10.1021/om00065a018

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