81106-32-3

Basic information

• Product Name: dimethylamino-2,N,N' diphenyl-1,3 diazaphospholane-1,3,2
• Synonyms: dimethylamino-2,N,N' diphenyl-1,3 diazaphospholane-1,3,2
• CAS NO: 81106-32-3
• Molecular Weight: 285.329
• Mol File: 81106-32-3.mol

Chemical Properties

• CAS DataBase Reference: dimethylamino-2,N,N' diphenyl-1,3 diazaphospholane-1,3,2(CAS DataBase Reference)
• NIST Chemistry Reference: dimethylamino-2,N,N' diphenyl-1,3 diazaphospholane-1,3,2(81106-32-3)
• EPA Substance Registry System: dimethylamino-2,N,N' diphenyl-1,3 diazaphospholane-1,3,2(81106-32-3)

Safety Data

• Hazardous Substances Data: 81106-32-3(Hazardous Substances Data)

Upstream product

• 150-61-8 N,N'-diphenylethylenediamine 
• 1608-26-0 Hexamethylphosphorous triamide 

Downstream Products

• 629-27-6 1-Iodooctane 
• 111-83-1 1-bromo-octane 
• 85558-01-6 2-Octyloxy-1,3-diphenyl-[1,3,2]diazaphospholidine 
• 2216-35-5 2-bromononane 
• 85558-02-7 2-(1-Methyl-octyloxy)-1,3-diphenyl-[1,3,2]diazaphospholidine 
• 85558-04-9 2-(2,2-Dimethyl-propoxy)-1,3-diphenyl-[1,3,2]diazaphospholidine 
• 81106-25-4 dimethylamino-2, N,N' phenylamino-1,3, N ethylimino-2, diazaiminophospholane-1,3,2 
• 85557-97-7 2-[(3S,5S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-Dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yloxy]-1,3-diphenyl-[1,3,2]diazaphospholidine 
• 85557-99-9 2-((1R,2R,4S)-Bicyclo[2.2.1]hept-2-yloxy)-1,3-diphenyl-[1,3,2]diazaphospholidine 
• 85557-99-9 2-((1S,2R,4R)-Bicyclo[2.2.1]hept-2-yloxy)-1,3-diphenyl-[1,3,2]diazaphospholidine 
• 85558-05-0 2-((3aR,4R,6R,6aR)-6-Methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethoxy)-1,3-diphenyl-[1,3,2]diazaphospholidine 
• 85558-06-1 2-[(3S,5S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-Dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yloxy]-1,3-diphenyl-[1,3,2]diazaphospholidine 2-sulfide 
• 85597-20-2 1,3-Diphenyl-2-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-ylmethoxy)-[1,3,2]diazaphospholidine 
• 81106-24-3 dimethylamino-2,diphenyl-1,3,phenylimino-2,diazaphospholane-1,3,2 

Relevant articles and documents

DESIGN AND REACTIVITY OF ORGANIC FUNCTIONAL GROUPS: THE HIGHLY CRYSTALLINE 2-ALKOXY N,N'-DIPHENYL-1,3,2-DIAZAPHOSPHOLANES AND THEIR FACILE CONVERSION INTO ALKYL HALIDES

Functionalization of alcohols as 2-alkoxy N,N'-diphenyl-1,3,2-diazaphospholanes affords highly crystalline derivatives useful for characterization purposes.These tervalent phosphorus derivatives undergo facile and mild conversion into the corresponding alkyl halides with inversion of configuration.

La liaison phosphazene dans quelques nouveaux iminophospholanes. Diversite de comportement reactionnel

Using the Staudinger reaction, we have synthesized twelve iminophospholanes (1-12) with dioxa (1-4), oxaza (5,6), and diaza (7-12) ring systems.We have never observed any phosphazene bond dimerization with diazaphospholane compounds, whatever the nature of the group on the imino atom.For the tetramethyl dioxaphospholane compounds (1,2,4), the thermal rearrangement occurs with the intracyclic oxygen atom.Last of all, the reactivity of the phosphazene bond with methanol differs according to the nature of the ring: addition leading to the pentacoordinated species in pinacolic compounds, intermolecular associations (hydrogen bonding) in diazaphospholane derivatives.