81120-67-4Relevant academic research and scientific papers
Total Synthesis of Amphoteronolide B and Amphotericin B. 1. Strategy and Stereocontrolled Construction of Key Building Blocks
Nicolaou, K. C.,Daines, R. A.,Uenishi, J.,Li, W. S.,Papahatjis, D. P.,Chakraborty, T. K.
, p. 4672 - 4685 (2007/10/02)
The retrosynthetic analysis and strategy for the total synthesis of amphotericin B (1) and amphoteronolide B (2) is discussed.Focusing on subtle and repeated structural units, a retrosynthetic scheme was constructed that led to the recognition of readily
Synthesis of Saccharides and Related Polyhydroxylated Natural Products. 2. Simple Deoxyalditols
Ma, P.,Martin, V. S.,Masamune, S.,Sharpless, K. B.,Viti, S. M.
, p. 1378 - 1380 (2007/10/02)
Asymmetric epoxidation of allylic alcohols followed by selective hydride reduction provides a new route to chiral 1,3-diols and 1,3,5-triols; one of the 1,3,5-triols (21) is also synthesized from D-glucose.
