81194-40-3

Basic information

• Product Name: Benzene, 1,1',1''-(1-ethenyl-1-ethanyl-2-ylidene)tris-
• CAS NO: 81194-40-3
• Molecular Formula: C22H20
• Molecular Weight: 284.401
• Mol File: 81194-40-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1',1''-(1-ethenyl-1-ethanyl-2-ylidene)tris-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1',1''-(1-ethenyl-1-ethanyl-2-ylidene)tris-(81194-40-3)
• EPA Substance Registry System: Benzene, 1,1',1''-(1-ethenyl-1-ethanyl-2-ylidene)tris-(81194-40-3)

Safety Data

• Hazardous Substances Data: 81194-40-3(Hazardous Substances Data)

Upstream product

• 91-01-0 1,1-Diphenylmethanol 
• 19752-23-9 cinnamyltrimethylsilane 
• 40595-34-4 (E)-trimethyl(3-phenylallyl)silane 
• 853-83-8 N-tosyldiphenylmethylamine 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 100-52-7 benzaldehyde 
• 79328-17-9 3-dimethylphenylsilyl-1-phenyl-1-propene 

Relevant articles and documents

Synthesis of Allylsilanes via Nickel-Catalyzed Cross-Coupling of Silicon Nucleophiles with Allyl Alcohols

NiCl2(PMe3)2-catalyzed reaction of allyl alcohols with silylzinc reagents, including PhMe2SiZnCl, Ph2MeSiZnCl, and Ph3SiZnCl, was performed, achieving allylsilanes in high yields. Aryl- and heteroaryl-substituted allyl alcohols, (E)-3-arylprop-2-en-1-ols, 1-aryl-prop-2-en-1-ols, and (E)-1-phenylpent-1-en-3-ol can be employed in the transformation. A range of functional groups as well as heteroaryl groups were tolerated. Reaction exhibited high regioselectivity and E/Z-selectivity when 1- or 3-aryl-substituted allyl alcohols were used as the substrates. Reaction of chiral allyl alcohol, (S,E)-1-phenylpent-1-en-3-ol, yielded a configuration-inversion product (R,E)-dimethyl(phenyl)(1-phenylpent-1-en-3-yl)silane.

Catalytic coupling of N-benzylic sulfonamides with silylated nucleophiles at room temperature

In the presence of 2-10 mol% of Tf2NH, a range of N-benzylic sulfonamides smoothly react with allylic, propargylic, benzylic, or hydrido silanes at room temperature via sp3 carbon-nitrogen bond cleavage to afford structurally diverse products in moderate to excellent yields and with high chemo- and regioselectivity.

Direct substitution of the hydroxy group in alcohols with silyl nucleophiles catalyzed by indium trichloride

Straightforward substitution: An excellent combination of a silyl nucleophile and indium catalyst was used to accomplish the dehydroxylation/ alkylation of alcohols under nearly neutral conditions (see scheme, Si = silyl group) even though this type of reaction usually requires at least an equimolar amount of acid.