81307-66-6

Upstream product

• 43179-48-2 L-arabinose di(ethylthio)acetal 
• 94898-36-9 (2R,3S,4S,5S)-dimethyl 2-acetoxy-3,4,5-tribenzyloxy-1,1-cyclohexane dicarboxylate 
• 94898-39-2 (1S,2S,3S,4S,5S)-4-acetoxy-5-acetoxymethyl-1,2,3-tribenzyloxycyclohexane 
• 94921-22-9 (3S,4S,5S)-3,4,5-Tris-benzyloxy-2-hydroxy-cyclohexane-1,1-dicarboxylic acid dimethyl ester 
• 94898-37-0 (3S,4S,5S)-3,4,5-Tris-benzyloxy-cyclohex-1-enecarboxylic acid methyl ester 
• 94898-44-9 (2R,3S,4S)-1,1-bis(ethylsulfanyl)-5-(trityloxy)pentane-2,3,4-triol 
• 94898-38-1 (3S,4S,5S)-3,4,5-tribenzyloxy-1-hydroxymethyl-1-cyclohexene 
• 94898-48-3 Toluene-4-sulfonic acid (2S,3S,4R)-2,3,4-tris-benzyloxy-5-oxo-pentyl ester 
• 94898-49-4 2,3,4-tri-O-benzyl-5-deoxy-5-iodo-L-arabinose 
• 94898-46-1 2,3,4-tri-O-benzyl-L-arabinose diethyl dithioacetal 
• 125258-11-9 DL-(1,2,4/3,5)-1,2,3-tri-O-benzyl-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 94943-07-4 (1S,2S,3S,4S,5S)-5-(acetoxymethyl)cyclohexane-1,2,3,4-tetrayl tetraacetate 
• 94898-39-2 (1S,2S,3S,4R,5R)-4-acetoxy-5-acetoxymethyl-1,2,3-tribenzyloxycyclohexane 
• 94943-06-3 (1S,2S,3S,4R,5R)-1,2,3,4-tetraacetoxy-5-acetoxymethylcyclohexane 

Downstream Products

• 20097-36-3 (1R,2R,3R,4S,5S)-cyclohexane-1,2,3,4,5-pentayl pentaacetate 
• 81623-40-7 L-1,2,5/3,4-cyclohexanepentol 

Relevant academic research and scientific papers

Synthesis and biological activities of D-chiro-inositol analogues with insulin-like actions

D-chiro-inositol (DCI, 1) evokes therapeutic actions in diabetes and insulin resistance but has sub-optimal pharmacokinetic profiles. To investigate what positions on the DCI cyclohexanol ring may be amenable to modification to improve pharmaceutical form

Stereoselective syntheses of racemic quercitols and bromoquercitols starting from cyclohexa-1,4-diene: Gala-, epi-, muco-, and neo-quercitol

The efficient synthesis of gala-, epi-, neo-, and muco-quercitols and some brominated quercitols starting from cyclohexa-1,4-diene is reported. Treatment of the dibromide, obtained by the addition of bromine to cyclohexa-1,4-diene, with m-chloroperbenzoic

SYNTHESIS OF OPTICALLY ACTIVE PSEUDO-α-D-GLUCOSE AND PSEUDO-β-L-ALTROSE

Optically active two pseudo-sugars, pseudo-α-D-glucose and pseudo-β-L-altrose have been synthesized by cyclization of 2,3,4-tri-O-benzyl-5-deoxy-5-iodo-L-arabinose with dimethyl malonate in the presence of sodium hydride as a key reaction.

THE PREPARATION OF CYCLOHEXANEPENTOLS FROM INOSITOLS BY DEOXYGENATION

Several cyclohexapenetols heva been synthesized from inositols by blocking all but one hydroxyl group, converting the free hydroxyl group into its S-methyl dithiocarbonate, and treating it with tributylstannane.Suitable blocking-groups are methyl, benzyl, and methylthiomethyl ethers, and acetals.One cyclohexanepentol was prepared by the reductive deamination of an aminodeoxyinositol.