81328-70-3Relevant academic research and scientific papers
Synthesis of dl-3-Hydroxycuparene by a Claisen Rearrangement of Allyl Aryl Ether
Inouye, Yoshinobu,Inomata, Satoru,Ishihara, Yasumasa,Kakisawa, Hiroshi
, p. 208 - 211 (2007/10/02)
The Claisen rearrangement of 1-methyl-2-cyclopentene in N,N-dimethylformamide gave 5-methyl-2-(1-methyl-2-methylenecyclopentyl)phenol (5) via its trimethylsilyl ether. The methylation of 5, followed by a Simmons-Smith reaction and by the catalytic hydrogenolysis, afforded 3-hydroxycuparene.
