81336-06-3

Basic information

• Product Name: Benzonitrile, 4-(1-hydroxy-1-methyl-3-butenyl)-
• CAS NO: 81336-06-3
• Molecular Formula: C12H13NO
• Molecular Weight: 187.241
• Mol File: 81336-06-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 4-(1-hydroxy-1-methyl-3-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 4-(1-hydroxy-1-methyl-3-butenyl)-(81336-06-3)
• EPA Substance Registry System: Benzonitrile, 4-(1-hydroxy-1-methyl-3-butenyl)-(81336-06-3)

Safety Data

• Hazardous Substances Data: 81336-06-3(Hazardous Substances Data)

Upstream product

• 1443-80-7 4-cyanophenyl methyl ketone 
• 762-73-2 trimethyl(allyl)stannane 
• 106-95-6 allyl bromide 
• 556-56-9 allyl iodid 

Relevant articles and documents

Noticeable facilitation of the bismuth-mediated Barbier-type allylation of aromatic carbonyl compounds under solvent-free conditions

When milled together with bismuth shot in the presence of allyl halide, aromatic aldehydes readily underwent a Barbier-type allylation to afford the corresponding homoallyl alcohols in good yield. In contrast to the failure in solution reaction, aromatic

THE REACTION OF ALLYL IODIDE WITH KETONES IN THE PRESENCE OF CERIUM AMALGAM. AN EFFICIENT METHOD FOR THE PREPARATION OF HOMOALLYLIC ALCOHOLS

Allyl iodide reacts in situ with cerium amalgam to generate allyl cerium iodide, which in turn reacts with ketones to yield homoallylic alcohols in good yields.