81336-06-3Relevant academic research and scientific papers
Noticeable facilitation of the bismuth-mediated Barbier-type allylation of aromatic carbonyl compounds under solvent-free conditions
Wada, Shinobu,Hayashi, Nobuyuki,Suzuki, Hitomi
, p. 2160 - 2163 (2007/10/03)
When milled together with bismuth shot in the presence of allyl halide, aromatic aldehydes readily underwent a Barbier-type allylation to afford the corresponding homoallyl alcohols in good yield. In contrast to the failure in solution reaction, aromatic
Photoinduced Allylation of Aromatic Carbonyl Compounds by Allylic Stannanes
Takuwa, Akio,Tagawa, Hiroyuki,Iwamoto, Hidetoshi,Soga, Osamu,Marayuma, Kazuhiro
, p. 1091 - 1094 (2007/10/02)
irradiation of aromatic carbonyl compounds and allyl-, 2-methyl-2-propenyl, or 3-methyl-2-butenyltrimethylstannanes in acetonitrile afforded δ,γ-unsaturated alcohols as major product.A photoinduced electron transfer mechanism is proposed for the allylations.
THE REACTION OF ALLYL IODIDE WITH KETONES IN THE PRESENCE OF CERIUM AMALGAM. AN EFFICIENT METHOD FOR THE PREPARATION OF HOMOALLYLIC ALCOHOLS
Imamoto, Tsuneo,Hatanaka, Yasuo,Tawarayama, Yoshinori,Yokoyama, Masataka
, p. 4987 - 4988 (2007/10/02)
Allyl iodide reacts in situ with cerium amalgam to generate allyl cerium iodide, which in turn reacts with ketones to yield homoallylic alcohols in good yields.
