81336-56-3Relevant academic research and scientific papers
A novel reaction of benzoyl chloride adduct of aromatic N-oxide with carbonitrile via a carbene intermediate
Tagawa, Yoshinobu,Tanaka, Jun'ichi,Hama, Kazuya,Goto, Yoshinobu,Hamana, Masatomo
, p. 69 - 72 (1996)
A carbene intermediate is proposed as a reactive species in the base-induced reaction of benzoyl chloride adducts of pyridine and quinoline N-oxides with carbonitriles to give 2-pyridyl- and 2-quinolyl diacylamine as main products.
Base-catalyzed electrophilic substitution in 2(1H)-quinolinones
Gonzales, Rosario,Ramos, M. Teresa,Cuesta, Elena de la,Avendano, Carmen
, p. 315 - 322 (2007/10/02)
Instead of tandem conjugate addition-α-alkylation to C3=C4 double bond of 2(1H)-quinolinones, regioselective C3-lithiation and subsequent C3-alkylation takes place by reaction with two equivalents of n-butyllithium and several electrophiles.
