81357-01-9

Basic information

• Product Name: 4-trimethylsilylpent-3-en-2-one
• Synonyms: 4-trimethylsilylpent-3-en-2-one
• CAS NO: 81357-01-9
• Molecular Weight: 156.3
• Mol File: 81357-01-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-trimethylsilylpent-3-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4-trimethylsilylpent-3-en-2-one(81357-01-9)
• EPA Substance Registry System: 4-trimethylsilylpent-3-en-2-one(81357-01-9)

Safety Data

• Hazardous Substances Data: 81357-01-9(Hazardous Substances Data)

Upstream product

• 72653-47-5 α-chlorobutyl phenyl sulfide 
• 82201-98-7 4-trimethylsilyl-2-trimethylsilyloxypenta-2,3-diene 

Downstream Products

• 79239-11-5 4-methyl-2-phenyl-4-trimethylsilylpentan-2-ol 
• 82202-05-9 4-methyl-3-(1-phenylthioethyl)-4-trimethylsilyloctan-2-one 
• 83182-12-1 3-Benzenesulfinyl-4-methyl-4-trimethylsilanyl-octan-2-one 
• 82202-04-8 4-methyl-3-(1-phenylthioethyl)-4-trimethylsilylpentan-2-one 
• 82202-11-7 3-ethyl-4-methyl-oct-3-en-2-one 
• 83182-15-4 (Z)-3-phenylthio-4-trimethylsilylpent-3-en-2-one 
• 83182-18-7 (E)-3-phenylthio-4-trimethylsilylpent-3-en-2-one 
• 78080-40-7 (E)-4-phenylthiopent-3-en-2-one 
• 83182-19-8 (E)-3-phenylsulphinyl-4-trimethylsilylpent-3-en-2-one 
• 83182-16-5 (Z)-3-phenylsulphinyl-4-trimethylsilylpent-3-en-2-one 
• 70769-79-8 (Z)-4-phenylthiopent-3-en-2-one 
• 7299-55-0 pent-3-yn-2-one 
• 83182-36-9 4-chloro-3-phenylthio-4-trimethylsilylpentan-2-one 

Relevant articles and documents

THE SYNTHESIS OF αβ-UNSATURATED KETONES FROM β-SILYLENONES AND β-SILYLYNONES

Conjugate addition, followed by alkylation, bromination and desilyl-bromination make the β-silylketone (4) an a3d2-synthon (5) and the β-silylynone (6) a 2a3d2-synthon (7).