THE SYNTHESIS OF αβ-UNSATURATED KETONES FROM β-SILYLENONES AND β-SILYLYNONES

DOI: 10.1016/S0040-4020(01)93277-6

Source and publish data:

Tetrahedron p. 4027 - 4034 (1981)

Update date:2022-09-26

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Authors:

Fleming, Ian

Perry, David A.

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Article abstract of DOI:10.1016/S0040-4020(01)93277-6

Conjugate addition, followed by alkylation, bromination and desilyl-bromination make the β-silylketone (4) an a³d²-synthon (5) and the β-silylynone (6) a 2a³d²-synthon (7).

Full text of DOI:10.1016/S0040-4020(01)93277-6

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