78080-40-7

Upstream product

• 108-98-5 thiophenol 
• 123-54-6 acetylacetone 
• 931-59-9 benzenesulfenyl chloride 
• 15745-68-3 (E)-1-phenyl-3-phenylsulfanyl-2-propen-1-one 
• 78080-37-2 (E)-1-Phenyl-3-phenylsulfanyl-but-2-en-1-one 
• 81357-01-9 4-trimethylsilylpent-3-en-2-one 
• 83182-36-9 4-chloro-3-phenylthio-4-trimethylsilylpentan-2-one 

Downstream Products

• 15724-82-0 (Z)-1-phenyl-3-phenylsulfanyl-2-propen-1-one 
• 70769-75-4 (Z)-1-Phenyl-3-phenylsulfanyl-but-2-en-1-one 
• 70769-78-7 (Z)-4-Phenyl-4-phenylsulfanyl-but-3-en-2-one 
• 70769-84-5 3-hydroxy-1-phenylbutyl phenyl sulphide 
• 15745-68-3 (E)-1-phenyl-3-phenylsulfanyl-2-propen-1-one 
• 108-98-5 thiophenol 
• 78080-37-2 (E)-1-Phenyl-3-phenylsulfanyl-but-2-en-1-one 
• 882-33-7 diphenyldisulfane 
• 625-33-2 3-penten-2-one 

Relevant academic research and scientific papers

Cycloelimination of β-Silylethyl Sulphoxides: Alkene, Alkyne, and Vinylsilane-forming Reactions

The cycloelimination (1)->(3) of trimethylsilyl sulphenate from a β-silylethyl sulphoxide is slightly faster than the corresponding cycloelimination (2)->(3) of sulphenic acid itself.The former type of reaction can be used to form acetylenes (

Reduction of β-Arylthio- or β-Alkylthio-αβ-Unsaturated Ketones

The preparation and reduction of β-arylthio or β-alkylthio-αβ-unsaturated ketones (1) with lithium aluminium hydride or sodium borohydride have been examined.Reduction of the ketones (1) with lithium aluminium hydride gave αβ-unsaturated ketones (2), in which the olefinic (R1) and carbonyl (R2) substituents are reversed compared with the starting αβ-unsaturated ketone (1), or the saturated γ-hydroxy-sulphides (3).Reduction of the ketones (1) with sodium borohydride afforded only the αβ-unsaturated ketones (2).Reduction of (1) with sodium borohydride in the presence of metal halides gave the saturated ketones (5).