81496-48-2

Basic information

• Product Name: (1S,2R)-1-Methyl-2-phenyl-cyclohexanecarbaldehyde
• CAS NO: 81496-48-2
• Molecular Weight: 202.296
• Mol File: 81496-48-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,2R)-1-Methyl-2-phenyl-cyclohexanecarbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R)-1-Methyl-2-phenyl-cyclohexanecarbaldehyde(81496-48-2)
• EPA Substance Registry System: (1S,2R)-1-Methyl-2-phenyl-cyclohexanecarbaldehyde(81496-48-2)

Safety Data

• Hazardous Substances Data: 81496-48-2(Hazardous Substances Data)

Upstream product

• 1019020-13-3 Cyclohex-1-enecarboximidic acid ethyl ester 
• 1855-63-6 cyclohex-1-enecarbonitrile 
• 22546-81-2 cyclohex-1-enecarboxamide 
• 1826-67-1 vinyl magnesium bromide 
• 74500-37-1 (S)-2-{[1-Cyclohex-1-enyl-meth-(Z)-ylidene]-amino}-3,3-dimethyl-butyric acid tert-butyl ester 
• 74-88-4 methyl iodide 
• 14441-56-6 trans-2-phenylcyclohexane-1-carbaldehyde 
• 14441-56-6 Formyl-1-phenyl-2-trans-cyclohexan 
• 148279-12-3 2-(1-cyclohexenyl)-4-methoxymethyl-2-oxazoline 

Downstream Products

• 13185-53-0 (+/-)-trans-1-methylcyclohexane-1,2-dicarboxylic acid 
• 76704-91-1 (+/-)-cis-1-methylcyclohexane-1,2-dicarboxylic acid 
• 81452-96-2 1α-Methyl-2α-phenyl-cyclohexan-1β-carbonsaeure 
• 81452-97-3 (+/-)-(1R*,6R*)-1-methyl-2-phenylcyclohexanecarboxylic acid 

Relevant articles and documents

Asymmetric addition to chiral aromatic and unsaturated oxazolines using a novel chiral auxillary

By utilizing S-serine, both enantiomers of the reduced methoxyamino alcohol (12) were efficiently prepared. The corresponding oxazolines, prepared from these auxiliaries, showed favorable properties toward additions to naphthalenes 22 and cyclohexene, 27.

ASYMMETRIC SYNTHESIS OF 1,2-DISUBSTITUTED CYCLOALKANECARBOXALDEHYDES. PROCEDURES FOR THE HIGHLY STEREOSELECTIVE PREPARATION OF cis- AND trans-ISOMER

Procedures for the asymmetric synthesis of 1,2-disubstituted cycloalkanecarboxaldehydes (7) having asymmetric tertiary and quaternary carbon atoms in vicinal positions from the corresponding cycloalkenecarboxaldehydes (2) in high diastereomeric and enanti