81600-63-7Relevant articles and documents
A study of transesterification of chiral (-)-pinanediol methylboronic ester with various structurally modified diols
Roy, Chandra D.,Brown, Herbert C.
, p. 747 - 753 (2007)
The transesterification of chiral (-)-pinanediol methylboronic ester was studied with various structurally modified diols by 1H NMR to understand the factors influencing the unusual stability of this boronic ester as well as to find ways of recovering pinanediol from its methylboronic ester. In all the cases, reactions were allowed to proceed to equilibrium. The preliminary experiments indeed have shown some encouraging results (displacement of pinanediol up to 40-53%). Amongst cyclopentane-based cis-1,2-diols, endo-2-phenyl-exo,exo-2,3-norbornane-diol appeared to be the most effective diol in displacing pinanediol (38%). In the cases of pinane-based diols, the best result was obtained with 2-ethyl-6,6-dimethylbicyclo[3.1.1]heptane-cis-2,3-diol (53%). It was interesting to observe that the transesterification with 2-phenyl-6,6-dimethylbicyclo[3.1.1]heptane-cis-2,3-diol resulted in a 50% conversion after 4 days only, whereas the former diol took 24 days to reach equilibrium.
Synthesis and phytotoxicity of new ionic liquids incorporating chiral cations and/or chiral anions
Balczewski, Piotr,Bachowska, Barbara,Bialas, Tomasz,Biczak, Robert,Wieczorek, Wanda M.,Balinska, Agnieszka
, p. 1881 - 1892 (2007)
The aim of this work was to synthesize chiral ionic liquids as chiral solvents for organic synthesis and to evaluate the phyto(eco)toxicity of the new products and starting N-alkylimidazoles and their potential environmental influence on soil and plants.
Reactivity of dipinanyl diselenides functionalized at the C-10-position with-CH2O(Se)Ph,-OH and-OCPh3 substituents
Scianowski, Jacek,Szumera, Jakub,Pacuta, Agata J.,Rafi?ski, Zbigniew
, p. 272 - 284 (2017/03/09)
Terpenyl alcohols, (-)-nopol and (-)-myrtenol were efficiently applied in the synthesis of new diselenides. The pinane skeleton, as the core of the structure, was decorated at the C-10 position by hydroxyl and O-trityl groups, and also OPh and SePh substi