81634-65-3Relevant academic research and scientific papers
Homoallyl-cyclopropylcarbinyl cation manifold. Trimethylsilyl versus aryl stabilization
Creary, Xavier,O'Donnell, Benjamin D.,Vervaeke, Marie
, p. 3360 - 3368 (2008/02/03)
(Chemical Equation Presented) A series of E- and Z-1-aryl-5-trimethylsilyl- 3-buten-1-yl trifluoroacetates were solvolyzed in CD3CO2D, and rates of reaction as well as products derived from these reactions were determined. Hammett pl
PREPARATION AND SYNTHETIC APPLICATION OF 3-BROMOALLYLTRIMETHYLSILANE AS HYDROXYPROPENYL SYNTHONS
Nishiyama, Hisao,Narimatsu, Shinzo,Itoh, Kenji
, p. 5289 - 5292 (2007/10/02)
3-Trimethylsilylpropen-1-yl group, as hydroxypropenyl synthons, was easily introduced to several epoxides with the corresponding Grignard reagent derived from 3-bromoallyltrimethylsilane.The introduced skeleton of allyltrimethylsilane was regiospecificall
