81645-83-2

Basic information

• Product Name: 1H-Tetrazole, 5-[[(4-nitrophenyl)methyl]thio]-1-phenyl-
• Synonyms: 1H-Tetrazole, 5-[[(4-nitrophenyl)methyl]thio]-1-phenyl-;5-[(4-nitrobenzyl)sulfanyl]-1-phenyl-1H-tetrazole
• CAS NO: 81645-83-2
• Molecular Formula: C14H11N5O2S
• Molecular Weight: 313.33444
• Mol File: 81645-83-2.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1H-Tetrazole, 5-[[(4-nitrophenyl)methyl]thio]-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Tetrazole, 5-[[(4-nitrophenyl)methyl]thio]-1-phenyl-(81645-83-2)
• EPA Substance Registry System: 1H-Tetrazole, 5-[[(4-nitrophenyl)methyl]thio]-1-phenyl-(81645-83-2)

Safety Data

• Hazardous Substances Data: 81645-83-2(Hazardous Substances Data)

Upstream product

• 107-06-2 1,2-dichloro-ethane 
• 86-93-1 1-Phenyl-1H-tetrazole-5-thiol 
• 81-07-2 saccharin 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 81589-05-1 1-phenyl-5-trimethylsilylthio-1H-tetrazole 
• 100-14-1 4-nitrobenzyl chloride 
• 86-93-1 1-phenyl-1H-tetrazole-5-thiol 

Relevant articles and documents

Direct Synthesis of Thioethers from Carboxylates and Thiols Catalyzed by FeCl3

A new and efficient method has been developed for the synthesis of thioethers from carboxylates and thiols. The reaction proceeds via a Fe(III)-catalyzed direct displacement of carboxylates from benzylic or allylic esters by heterocyclic thiols. Short rea

Tetrazoles. XXXI. Phase-Transfer Reactions of 1-Substituted Tetrazole-5-thiones and Their Derivatives

Alkylation of 1-substituted tetrazole-5-thiones under conditions of phase-transfer catalysis in the two-phase system liquid-liquid proceeds regioselectively at the sulfur atom, regardless of the alkylating agent and phase-transfer catalyst. Phase-transfer oxidation of the 5-alkylthiotetrazoles thus obtained by potassium permanganate is a convenient method for preparation of 5-alkylsulfonyltetrazoles which can be used to synthesize functionally substituted tetrazoles.

Phenylmercaptotetrazolo- and nitroindazolo masked development/image modifiers

Novel nitrobenzyl compounds are incorporated into a photographic emulsion or developer for controlled release of development/image modifier compounds. This occurs imagewise only after developer oxidation products have been formed in the course of the development process. For example, nitrobenzyl-masked phenylmercaptotetrazole (PMT), incorporated into a silver halide emulsion, reacts with developer oxidation products via an electron transfer mechanism to release the potent development restrainer PMT.