81653-01-2

Upstream product

• 67470-70-6 (2S,3R)-2,3-Dihydroxy-4-methyl-5-phenylpent-4-ene 
• 77-76-9 2,2-dimethoxy-propane 
• 15174-47-7 α-methyl-trans-cinnamaldehyde 

Downstream Products

• 81653-02-3 C₁₄H₁₉NO₂S 
• 81653-09-0 (3aR,4S,7aR)-6-Ethoxy-4,7a-dimethyl-2-phenyl-3a,6,7,7a-tetrahydro-4H-pyrano[4,3-d]oxazole 
• 81653-03-4 N-[(S)-1-((1R,2S)-1,2-Dihydroxy-propyl)-1-methyl-but-3-enyl]-benzamide 
• 81703-35-7 N-[(R)-1-((1S,2S)-1,2-Dihydroxy-propyl)-1-methyl-but-3-enyl]-benzamide 
• 81653-08-9 N-benzoyl-L-vancosamine 
• 89822-01-5 N-((2S,3S,4S,6S)-3,6-Dihydroxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-benzamide 
• 81653-06-7 N-((2S,3R,4S,6R)-3,6-Dihydroxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-benzamide 
• 81653-07-8 N-((2S,3S,4R,6R)-3,6-Dihydroxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-benzamide 
• 89822-02-6 N-((2S,3S,4R,6S)-3,6-Dihydroxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-benzamide 
• 74966-76-0 N-((2S,3R,4S,6R)-3-Hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-benzamide 
• 85950-14-7 (6S,7S,8S)-6-benzyloxy-2,6-dimethyl-7,8-isopropylidenedioxynon-1-ene 
• 85950-15-8 (6S,7S,8S)-6-benzyloxy-2,6-dimethylnon-1-ene-7,8-diol 
• 81703-33-5 1-[(4S,5S)-2,2,5-trimethyl-1,3-dioxolan-4-yl]ethanone 
• 100-52-7 benzaldehyde 

Relevant academic research and scientific papers

SYNTHESIS OF THE N-BENZOYL DERIVATIVES OF L-ARABINO,L-XYLO AND L-LYXO (L-VANCOSAMINE) ISOMERS OF 2,3,6-TRIDEOXY-3-C-METHYL-3-AMINOHEXOSE FROM A NON-CARBOHYDRATE PRECURSOR

The synthesis of the N-benzoyl derivatives of L-arabino (10),L-xylo (13) and L-lyxo (L-vancosamine) (12) 2,3,6-trideoxy-3-C-methyl-3-aminohexose from the (2S,3R) diol (1) prepared in fermenting bakers' yeast from α-methylcinnamaldehyde and acetaldehyde is reported.

Synthesis of (-)-Frontalin from the (2S,3R)-Diol prepared from α-Methylcinnamaldehyde and Fermenting Baker's Yeast

The synthesis of (-)-frontalin (13) from the (2S,3R)-diol (2b), through the intermediacy of the C5 (3S,4S) methyl ketone (6) and of the C11 adduct (8), is reported.