85950-14-7

Upstream product

• 72535-09-2 4-methyl-4-penten-1-ylmagnesium bromide 
• 81703-33-5 1-[(4S,5S)-2,2,5-trimethyl-1,3-dioxolan-4-yl]ethanone 
• 67470-70-6 (2S,3R)-2,3-Dihydroxy-4-methyl-5-phenylpent-4-ene 
• 81653-01-2 (3R,4S)-3,4-isopropylidenedioxy-2-methyl-1-phenylpent-1-ene 
• 100-39-0 benzyl bromide 
• 85950-13-6 (6S,7S,8S)-7,8-isopropylidenedioxy-2,6-dimethylnon-1-en-6-ol 

Downstream Products

• 85963-44-6 (6S)-6-benzyloxy-6-methyl-2-vinylheptan-7-ol 
• 85950-16-9 (6S)-6-benzyloxy-7-hydroxy-6-methylheptan-2-one 
• 85950-15-8 (6S,7S,8S)-6-benzyloxy-2,6-dimethylnon-1-ene-7,8-diol 

Relevant academic research and scientific papers

Synthesis of (-)-Frontalin from the (2S,3R)-Diol prepared from α-Methylcinnamaldehyde and Fermenting Baker's Yeast

The synthesis of (-)-frontalin (13) from the (2S,3R)-diol (2b), through the intermediacy of the C5 (3S,4S) methyl ketone (6) and of the C11 adduct (8), is reported.