81679-53-0Relevant academic research and scientific papers
SELECTIVITY IN EPOXIDATION: ACYCLIC DIASTEREO- AND ENANTIO-SELECTION WITH PEROXIDE MEDIATED BY TITANIUM(IV) AND WITH PERACID
Isobe, Minoru,Kitamura, Masato,Mio, Shigeru,Goto, Toshio
, p. 221 - 224 (1982)
New diastereoselective epoxidation on the olefin 1 with TBHP mediated by Ti(IV) is described to give the epoxyde 2 which has reverse orientation of the one, 3, with MCPBA.Ti-mediation was ineffective on the olefin 4, on which MCPBA worked in high selectiv
