SELECTIVITY IN EPOXIDATION: ACYCLIC DIASTEREO- AND ENANTIO-SELECTION WITH PEROXIDE MEDIATED BY TITANIUM(IV) AND WITH PERACID

DOI: 10.1016/S0040-4039(00)86790-8

Source and publish data:

Tetrahedron Letters p. 221 - 224 (1982)

Update date:2022-08-02

Topics:

Authors:

Isobe, Minoru

Kitamura, Masato

Mio, Shigeru

Goto, Toshio

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Article abstract of DOI:10.1016/S0040-4039(00)86790-8

New diastereoselective epoxidation on the olefin 1 with TBHP mediated by Ti(IV) is described to give the epoxyde 2 which has reverse orientation of the one, 3, with MCPBA.Ti-mediation was ineffective on the olefin 4, on which MCPBA worked in high selectiv

Full text of DOI:10.1016/S0040-4039(00)86790-8

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