SELECTIVITY IN EPOXIDATION: ACYCLIC DIASTEREO- AND ENANTIO-SELECTION WITH PEROXIDE MEDIATED BY TITANIUM(IV) AND WITH PERACID

DOI: 10.1016/S0040-4039(00)86790-8

Source and publish data:

Tetrahedron Letters p. 221 - 224 (1982)

Update date:2022-08-02

Topics:

Authors:

Isobe, Minoru

Kitamura, Masato

Mio, Shigeru

Goto, Toshio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)86790-8

New diastereoselective epoxidation on the olefin 1 with TBHP mediated by Ti(IV) is described to give the epoxyde 2 which has reverse orientation of the one, 3, with MCPBA.Ti-mediation was ineffective on the olefin 4, on which MCPBA worked in high selectiv

Full text of DOI:10.1016/S0040-4039(00)86790-8

Products guided by the article

Product name:3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (2R,3R)-3-[(1R,2R)-6-acetoxy-2-(tert-butyl-dimethyl-silanyloxy)-4,4,5-trimethoxy-1-methyl-hexyl]-2-methyl-oxiranylmethyl ester

Cas No:81679-53-0

R&D Labs maybe for 81679-53-0

Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district
HEBEI BRANT PHARMACEUTICAL

Contact:+86-0311-84455288-844

Address:Mayu Industrial Park, Jinzhou, Hebei, China.
HANGZHOU YUNUO CHEMICAL CO.,LTD

website:http://www.yunuochem.com

Contact:0571-83715115

Address:hangzhou
Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China

Relevant to this article

Doi:10.1016/0040-4020(70)80010-2
(1970)
Copper-promoted sandmeyer difluoromethylthiolation of aryl and heteroaryl diazonium salts

Doi:10.1002/anie.201502113
(2015)
Stereochemistry of Biscopper(II) and nickel(II) Complexes

Doi:10.1246/bcsj.55.1083
(1982)
Syntheses of epi-β-santalene, β-santalene and an isomer of β-santalene with 4-methyl-4-pentenyl side chain

Doi:10.1080/00397919208021129
(1992)
Influence of material properties on the damage-reporting and self-healing performance of a mechanically active dynamic network polymer in coating applications

Doi:10.3390/molecules26092468
(2021)
Diastereoselective intramolecular temporary silicon-tethered rhodium-catalyzed [4+2+2] cycloisomerization reactions: Regiospecific incorporation of substituted 1,3-butadienes

Doi:10.1021/ja046030+
(2004)

Article Doi