81703-07-3Relevant academic research and scientific papers
Total synthesis of racemic 2-desoxystemodinone and stemodinol; the identity of natural "stemodinol" with stemarin
Kelly, Ronald B.,Harley, Mary Lou,Alward, Sandra J.,Manchand, Percy, S.
, p. 675 - 678 (1982)
Total synthesis of the naturally occuring diterpinoid 2-desoxystemodinone (3) and the diterpenoid structure 2 ("stemodinol") are described.The synthetic diterpenoid 2 was not identical to an authentic sample of "stemodinol".The authentic sample was found to be stemarin to which structure 2 had been erroneously assigned in the literature.It would appear that the diterpenoid represented by 2 has not been isolated from natural sources.
Total synthesis of the stemodane-type diterpenoids, (+/-)-2-desoxystemodinone, (+)-2-desoxystemodinone, and (+/-)-stemodinol
Kelly, Ronald B.,Harley, Mary Lou,Alward, Sandra J.,Rej, Rabindra N.,Gowda, Gopala,et al.
, p. 269 - 275 (2007/10/02)
Stereospecific total syntheses of (+/-)-2-desoxystemodinone, (+)-2-desoxystemodinone, and (+/-)-stemodinol are described.Also described are the isolation of (+)-2-desoxystemodinone from S. maritima and its characterization.A strategy for the elaboration o
