81841-44-3

Upstream product

• 55533-86-3 3-O-Benzyl-3-C-methyl-1,2-O-isopropylidene-α-D-allofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 35784-67-9 1,2;5,6-di-O-isopropylidene-3-C-methyl-α-D-allofuranose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 55533-85-2 3-O-benzyl-3-C-methyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 132000-22-7 (5R)-3-O-Benzyl-1,2-O-isopropylidene-3-C-methyl-5-(9',10'-dihydro-1',4'-dihydroxy-9',10'-dioxo-2'-anthryl)-α-D-ribofuranose 
• 132000-20-5 (5S)-3-O-Benzyl-1,2-O-isopropylidene-3-C-methyl-5-(9',10'-dihydro-1',4'-dihydroxy-9',10'-dioxo-2'-anthryl)-α-D-ribofuranose 
• 132000-31-8 (4R)-2-O-Benzyl-2-C-methyl-3-O-formyl-4-(1,2,3,4,4a,9,9a,10-octahydro-5-hydroxy-1,4,9,10-tetraoxo-2-anthryl)-α(β)-D-erythro-tetrafuranose 
• 132000-31-8 (4S)-2-O-Benzyl-2-C-methyl-3-O-formyl-4-(1,2,3,4,4a,9,9a,10-octahydro-5-hydroxy-1,4,9,10-tetraoxo-2'-anthryl)-α(β)-D-erythro-tetrafuranose 
• 132000-34-1 (5S)-3-O-Benzyl-3-C-methyl-5-(9',10'-dihydro-1',4',5'-trihydroxy-9',10'-dioxo-2-anthryl)-α,β-D-ribopyranose 
• 132000-34-1 (5R)-3-O-Benzyl-3-C-methyl-5-(9',10'-dihydro-1',4',5'-trihydroxy-9',10'-dioxo-2'-anthryl)-α-β-D-ribopyranose 
• 132000-33-0 (7R/S,8R,9S,10S)-8-O-Benzyl-3-C-methyl-7,8,9,10-tetrahydro-4,6,7,8,9,10,11-heptahydroxynaphthacene-5,12-dione 
• 132000-33-0 (7R/S)-8R,9S,10R-8-O-Benzyl-8-methyl-7,8,9,10-tetrahydro-4,6,8,9,10,11-heptahydroxynaphthacene-5,12-dione 
• 132000-30-7 (4R)-2-O-Benzyl-2-C-methyl-3-O-formyl-4-(9',10'-dihydro-1',4',5'-trihydroxy-9',10'-dioxo-2'-anthryl)-α(β)-D-erythro-tetrafuranose hemihydrate 
• 132000-30-7 (4S)-2-O-Benzyl-2-C-methyl-3-O-formyl-4-(9',10'-dihydro-1',4',5'-trihydroxy-9',10'-dioxo-2-anthryl)-α,β-D-erythro-tetrafuranose 
• 132000-23-8 (5S)-3-O-Benzyl-3-C-methyl-5-(9',10'-dihydro-1',4'-dihydroxy-9',10'-dioxo-2'-anthryl)-α,β-D-ribopyranose 
• 132000-37-4 (8R,9S,10S)-8-O-Benzyl-8-C-methyl-7,8,9,10-tetrahydro-4,6,8,9,10,11-hexahydroxynaphthacene-5,12-dione 
• 132000-32-9 (8R,9S,10R)-8-O-Benzyl-8-methyl-7,8,9,10-tetrahydro-4,6,8,9,10,11-hexahydroxynaphthacene-5,12-dione 
• 132000-27-2 (4S)-2-C-Methyl-2-O-benzyl-3-O-formyl-4-(9',10'-dihydro-1',4'-dihydroxy-9,10-dioxo-2-anthryl)-α,β-D-erythro-tetrafuranose 

Relevant academic research and scientific papers

ANTHRACYCLINONES. PART VIII. SYNTHESIS OF A 9-METHYL ANTHRACYCLINONE FROM D-GLUCOSE

The chiral pool synthesis of enantiomerically pure anthracyclinone 6 from leucoquinizarin 10, and from 3-O-benzyl-1,2-O-isopropylidene-3-C-methyl-α-D-ribo-pentodialdo-1,4-furanose (9) readily obtained from diacetone glucose, is reported.

Anthracyclinones. Part 5. Synthesis of Some Anthracyclinones and 4-Hydroxyanthracyclinones containing a Tertiary Methyl Carbinol Function in Ring A from D-Glucose Precursors

Reaction of 3-C-Methyl-1,2-O-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose (8a) with leucoquinizarin (2,3,4a,9a-tetrahydroanthracene-1,4,9,10-tetraone) (1a) in alkaline solution followed by aerial oxidation gave mainly (5S)-3-C-methyl 1,2-O-isopropylid

BRANCHED CHAIN SUGARS. XXVIII. SYNTHESIS OF 2-C-METHYL-L-GLYCERALDEHYDE, 2-C-METHYL-D-ERYTHROSE, AND 3-C-METHYL-L-ERYTHROSE DERIVATIVES

As synthons for the synthesis of bicyclomycin, the title compounds were derived from 1,2:5,6-di-O-isopropylidene-3-C-methyl-α-D-allofuranose bythe descendent method.