81857-39-8

Upstream product

• 57812-97-2 CH₃OC₆H₅Mn(CO)3 
• 89672-80-0 anisolemanganese tricarbonyl tetrafluoroborate 
• 100-59-4 phenylmagnesium chloride 

Downstream Products

• 898837-74-6 (η5-2-methoxy-3-methyl-6-phenylcyclohexadienyl)Mn(CO)3 
• 898837-78-0 (η5-2-methoxy-3-iodo-6-phenylcyclohexadienyl)Mn(CO)3 
• 898837-70-2 (η5-2-methoxy-3-(trimethylsilyl)-6-phenylcyclohexadienyl)Mn(CO)3 
• 898837-76-8 (η5-2-methoxy-3-(CO2Et)-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-65-3 (η5-2-methoxy-3-(phenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3 
• 898837-75-7 (η5-2-methoxy-3-(diphenylhydroxymethyl)-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-51-7 (η5-2-methoxy-3-D-6-phenylcyclohexadienyl)Mn(CO)3 
• 898837-77-9 (η5-2-methoxy-3-(tri-n-butylstannyl)-6-phenylcyclohexadienyl)Mn(CO)3 
• 1219716-81-0 (CH₃OC₆H₄CHOHC₄H₃SC₆H₅)Mn(CO)3 
• 1345735-66-1 [(η5-MeOC6H4(Ph)CH(OH)Fc)Mn(CO)3] 

Relevant academic research and scientific papers

Ferrocenyl-substituted (μ5-hydroxyalkylcyclohexadienyl) tricarbonylmanganese complexes: Synthesis, structural determinations, and formation of carbenium ions

Ferrocenyl-substituted (μ5-hydroxyalkylcyclohexadienyl) -tricarbonylmanganese complexes have been synthesized as well as the corresponding carbenium dinuclear complexes after dehydroxylation. Studies in solution and in the solid state of these zwitterionic species show not only the electronic influence of the positive charge on the μ5-Mn complex but also the participation of the two metal atoms in the stabilization of this charge. Catalytic tests show a high activity of these cations as Lewis acids in a typical Diels-Alder reaction.

Addition of grlgnard reagents and ketone enolates to the arene in (arene) manganese tricarbonyl cations

Grignud reagents and Intone eoolAWfi odd to the tittot ring in [(aroDilMn(CO)3] to give food yields of thermally liable cycloheiadienyl compleiei which are eaiily oxidized with Jonee trafftnt to pvt its functioned UBDID, A mnbod to frit to runctinmilid rtnq that ullnwi iwUtion nod recycling nf the Mil (CO) j^ moiety ia olio dticribed. Addition to nubfttitutd arenet it fthown to be regioaelective in prcdicUiblt mjinntr It Ham ihut the (urenakmuiguieH compleiti wi prove to be of igiiificflnt utility in urguuo syntheui