81872-32-4

Basic information

• Product Name: 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-5-C-(p-tolylsulfonylhydrazino)-α-D-xylo-hexofuranose
• CAS NO: 81872-32-4
• Molecular Weight: 722.796
• Mol File: 81872-32-4.mol

Chemical Properties

• CAS DataBase Reference: 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-5-C-(p-tolylsulfonylhydrazino)-α-D-xylo-hexofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-5-C-(p-tolylsulfonylhydrazino)-α-D-xylo-hexofuranose(81872-32-4)
• EPA Substance Registry System: 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-5-C-(p-tolylsulfonylhydrazino)-α-D-xylo-hexofuranose(81872-32-4)

Safety Data

• Hazardous Substances Data: 81872-32-4(Hazardous Substances Data)

Upstream product

• 7162-15-4 methyl phenylphosphinate 
• 81823-13-4 3,6-Di-O-benzyl-1,2-O-isopropylidene-α-D-xylo-hexofuranos-5-ulose(E,Z)-5-(p-tolylsulfonyl)hydrazone 

Downstream Products

• 81823-18-9 1,2,4-tri-O-acetyl-3,6-di-O-benzyl-5-deoxy-5-C-(phenylphosphinyl)-β-D-glucopyranose 
• 81823-18-9 Acetic acid (3R,4S,5S)-3,5-diacetoxy-4-benzyloxy-6-benzyloxymethyl-1-oxo-1-phenyl-1λ⁵-phosphinan-2-yl ester 
• 81835-18-9 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-(phenylphosphinyl)-α-D-xylo-hexofuranose 
• 81823-16-7 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-α-D-xylo-hexofuranose 

Relevant articles and documents

SYNTHESIS OF 1,2,4-TRI-O-ACETYL-3,6-DI-O-BENZYL-5-DEOXY-5-C--β-D-GLUCOPYRANOSE: THE FIRST gluco TYPE OF HEXOPYRANOSE DERIVATIVE HAVING PHOSPHORUS IN THE HEMIACETAL RING

Oxidation of 3,6-di-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose with pyridinium chlorochromate in the presence of molecular sieves, followed by conversion into the p-tolylsulfonylhydrazone, addition of methyl phenylphosphinate, and reduction with sodi