1431-22-7Relevant academic research and scientific papers
Nitration of steroidal olefins with sodium nitrite
Goswami, Papori,Chowdhury
, p. 1221 - 1222 (2007/10/03)
Δ5-Steroidal olefins react with the sodium nitrite-acetyl chloride system to furnish 5α-chloro-6β-nitro derivatives in good yields while Δ5, 16-20-oxo-steroids furnish regioselectively vinyl nitro derivatives Δ5, 16-16-nitro-20-oxosteroids.
Preparation of chloro-nitrocompounds from olefins by in situ generation of nitrosyl chloride from chlorotrimethylsilane and sodium nitrite
Chowdhury, Pritish K.,Barbaruah, Moheswar,Sharma, Ram P.
, p. 71 - 72 (2007/10/02)
Olefins react with chlorotrimethylsilane and sodium nitrite to furnish the corresponding chloro-nitro derivatives.The resulted chloro-nitro derivatives undergo reductive elimination to the corresponding olefins by nickel boride generated in situ from nick
