82065-58-5

Upstream product

• 82065-66-5 (4S,6R)-4-(2-Benzyloxy-ethyl)-6-but-3-enyl-2,2-dimethyl-[1,3]dioxane 
• 100-39-0 benzyl bromide 
• 85539-44-2 Carbamic acid (E)-(R)-5-benzyloxy-1-but-3-enyl-pent-3-enyl ester 
• 85539-52-2 (E)-(R)-9-Benzyloxy-nona-1,7-dien-5-ol 
• 89009-90-5 ((R)-6-But-3-enyl-2,2-dimethyl-[1,3]dioxan-4-yl)-acetic acid ethyl ester 
• 104801-92-5 methyl (R)-3-[(tetrahydro-2H-pyran-2-yl)oxy]-6-heptenoate 
• 82065-65-4 (R)-3-[(tetrahydro-2H-pyran-2-yl)oxy]-6-heptenal 

Downstream Products

• 82080-54-4 (3E,9E,11E)-(S)-1-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-8-(tert-butyl-dimethyl-silanyloxy)-trideca-3,9,11-trien-5-one 

Relevant academic research and scientific papers

CARBAMATE MEDIATED 1,3-ASYMMETRIC INDUCTION. A STEREOSELECTIVE SYNTHESIS OF ACYCLIC 1,3-DIOL SYSTEMS.

A highly regio- and stereo-selective functionalization of homoallylic carbamates with iodine is reported.The reaction has been applied to the preparation of key 1,3,5-triol intermediate 2 employed in the synthesis of compactin (1).