85539-44-2

Upstream product

• 85539-51-1 (E)-(R)-5-(Tetrahydro-pyran-2-yloxy)-nona-2,8-dienoic acid methyl ester 
• 82065-65-4 (R)-3-[(tetrahydro-2H-pyran-2-yl)oxy]-6-heptenal 
• 100-39-0 benzyl bromide 
• 85539-52-2 (E)-(R)-9-Benzyloxy-nona-1,7-dien-5-ol 
• 3019-71-4 Trichloroacetyl isocyanate 

Downstream Products

• 82065-66-5 (4S,6R)-4-(2-Benzyloxy-ethyl)-6-but-3-enyl-2,2-dimethyl-[1,3]dioxane 
• 82065-58-5 3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-propionaldehyde 
• 85539-48-6 (4R,6R)-4-((S)-2-Benzyloxy-1-iodo-ethyl)-6-but-3-enyl-[1,3]dioxan-2-one 
• 85539-49-7 Carbamic acid (R)-1-((2R,3S)-4-benzyloxy-2-hydroxy-3-iodo-butyl)-pent-4-enyl ester 

Relevant academic research and scientific papers

CARBAMATE MEDIATED 1,3-ASYMMETRIC INDUCTION. A STEREOSELECTIVE SYNTHESIS OF ACYCLIC 1,3-DIOL SYSTEMS.

A highly regio- and stereo-selective functionalization of homoallylic carbamates with iodine is reported.The reaction has been applied to the preparation of key 1,3,5-triol intermediate 2 employed in the synthesis of compactin (1).