82125-29-9Relevant academic research and scientific papers
Directed ortho metalation of O-aryl and O-pyridyl thiocarbamates. A versatile synthetic method for substituted phenol into thiophenol conversion
Beaulieu,Snieckus
, p. 112 - 118 (2007/10/02)
The preparation of ortho-substituted O-aryl and O-pyrid-3-yl thiocarbamates 7a-h and 11a-d and anionic ortho-Fries rearrangements of selected cases [O-phenyl N,N-diethylthiocarbamate (6a) → N,N-diethyl-2-hydroxy-3-methylbenzenecarbothioamide (9), O-[4-(tr
Conversion of sterically hindered phenols into the corresponding N,N-dimethylarenesulfonamides via the Newman-Kwart rearrangement
Wagenaar, Anno,Engberts, Jan B. F. N.
, p. 91 - 94 (2007/10/02)
The 2-alkyl- and 2,6-dialkylbenzenesulfonyl chlorides 5a-f were obtained in high yield by chlorination of the correspondingly substituted S-aryl N,N-dialkylthiocarbamates 4a-g.These precursors have been synthesized via the Newman-Kwart rearrangement of th
