82134-96-1

Basic information

• Product Name: L-Ascorbic Acid 2-(Dihydrogen Phosphate) CyclohexanaMine-13C6
• Synonyms: L-Ascorbic Acid 2-(Dihydrogen Phosphate) CyclohexanaMine-13C6;PUVHGDVAGFEKER-KXLAEFBNSA-N
• CAS NO: 82134-96-1
• Molecular Formula: C12H22NO9P
• Molecular Weight: 355.278141
• Product Categories: Carbohydrates & Derivatives, Isotope Labelled Compounds, Pharmaceuticals, Intermediates & Fine Chemicals
• Mol File: 82134-96-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: L-Ascorbic Acid 2-(Dihydrogen Phosphate) CyclohexanaMine-13C6(CAS DataBase Reference)
• NIST Chemistry Reference: L-Ascorbic Acid 2-(Dihydrogen Phosphate) CyclohexanaMine-13C6(82134-96-1)
• EPA Substance Registry System: L-Ascorbic Acid 2-(Dihydrogen Phosphate) CyclohexanaMine-13C6(82134-96-1)

Safety Data

• Hazardous Substances Data: 82134-96-1(Hazardous Substances Data)

Usage

Uses

Isotope Labelled L-Ascorbic Acid 2-(Dihydrogen Phosphate) Cyclohexanamine is a derivative of L-Ascorbic Acid (A786990), an coenzyme for a number of hydroxylation reactions; required for collagen synthesis.

Upstream product

• 55517-56-1 2,3,5,6-tetrakis-O-(trimethylsilyl) ascorbate 
• 82134-97-2 (3aR,6S,6aR)-3a,6-Bis-trimethylsilanyloxy-tetrahydro-furo[3,2-b]furan-2,3-dione 
• 108-91-8 cyclohexylamine 

Relevant articles and documents

Silyl Phosphites. 21. A New Method for the Synthesis of L-Ascorbic Acid 2-O-Phosphate by Utilizing Phosphoryl Rearrangement

A stabilized form of vitamin C, L-ascorbic acid 2-O-phosphate (1), was successfully synthesized by a new method via a fully trimethylsilylated L-ascorbic acid (4) that was prepared in high yield by silylation of L-ascorbic acid with hexamethyldisilazane.Bromination of 4 gave an adduct (6) that was isomerized during distillation to a trimethylsilylated bicyclic half acetal (8) of dehydroascorbic acid.Addition of tris(trimethylsilyl) phosphite (TMSP) to 8 gave carbonyl addition compounds 9a and 9b, which underwent thermal rearrangement to give a mixture of bis(trimethylsilyl)-3,5,6-tris-O-(trimethylsilyl)-L-ascorbic acid 2-O-phosphate (10) and its 3-O-isomer 13 in the ratio of 88:12.Treatment of the mixture with cyclohexylamine in methanol gave selectively tricyclohexylammonium salt of L-ascorbic acid 2-O-phosphate in 53percent yield.