82290-07-1

Basic information

• Product Name: ethyl ester of 3-methoxy-2-propen-1-oic acid
• Synonyms: ethyl ester of 3-methoxy-2-propen-1-oic acid
• CAS NO: 82290-07-1
• Molecular Weight: 130.144
• Mol File: 82290-07-1.mol

Chemical Properties

• Boiling Point: 74-77 °C(Press: 16 Torr)
• Density: 0.9653 g/cm3(Temp: 18.5 °C)
• CAS DataBase Reference: ethyl ester of 3-methoxy-2-propen-1-oic acid(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl ester of 3-methoxy-2-propen-1-oic acid(82290-07-1)
• EPA Substance Registry System: ethyl ester of 3-methoxy-2-propen-1-oic acid(82290-07-1)

Safety Data

• Hazardous Substances Data: 82290-07-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 623-47-2 propynoic acid ethyl ester 

Downstream Products

• 6214-29-5 3-methoxy-2-propen-1-oic acid 

Relevant articles and documents

Platinum- and gold-catalyzed hydroalkoxylation and tetramerization of propiolate esters

PtCl2 was found to efficiently catalyze intermolecular additions of propiolate esters with alcohols. The reaction of propiolate esters and alcohols in the presence of PtCl2 gave (E)-vinyl ethers as the major products at 60 °C, whereas alkyl 3,3-dialkoxypropanoates were predominantly obtained when the reaction temperature was set to 80°C. On the other hand, a novel regioselective tetramerization of propiolate esters catalyzed by AuCl3 under mild conditions afforded 1,2,5,6-tetrasubstituted- cyclooctatetraene (1,2,5,6-COT) in moderate yields.